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(R)-(-)-联萘酚磷酸酯
Product No.:SRCHEM0003
De
Synonyms:
(R)-4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-oxide
(R)-(-)-BNP ACID
Structural Formula:
Molecular Formula: C20H13O4P
Molecular Weight: 348.29
CAS Number: 39648-67-4
Beilstein Registry Number: 4713363
PubChem Substance ID: 24854961
Application:
A chiral ligand used in hydrocarboxylation reactions. Complexes with rhodium and mediates the asymmetric dipolar cycloaddition of diazo compounds. A number of racemic amines which have proven difficult to separate have been resolved with this chiral acid. Palladium derivatives have been used in asymmetric hydrocarboxylations, and rhodium derivatives have been used in dipolar cycloadditions. Used in a chiral Bronsted acid catalyzed enantoselective Mannich reaction.
Standards:
Appearance: white powder
Chiral Assay(HPLC):ee: 99.%ee+ ( optical purity)
Chemical Assay(HPLC): 99.%+
optical activity：([a]22/D): -605°, c = 1.35 in CH3OH
Melting Point: 300°C
Loss on drying: 0.10%
Packaging specifications:
Cardboard drum Packaging:
5kgs/ drum. 10kgs/ drum. 20kgs/ drum.
:Reagent Packaging:
100g/ Bottle. 500g/ Bottle. 1kgs/ Bottle.
FT-IR Condensed Phase
References:
Fieser: Fieser12,49
Fieser16,25
Reference: FT-IR2(2), 3365:D
FT-IR1(2), 562:B
RegBook1(2), 2295:G
Sigma FT-IR1(2), 323:D
Structure Index1, 359:D:5
Safety
Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
